Issue 3, 1984

Base hydrolysis of the penta-ammine(trimethyl phosphate)iridium(III) ion

Abstract

The base hydrolysis of trimethyl phosphate to yield dimethyl phosphate and methanol is accelerated 400- fold upon co-ordination to the penta-ammineridium(III) moiety; the reaction proceeds via intermolecular attack of hydroxide ion at the phosphorus center in both co-ordinated and free ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 164-165

Base hydrolysis of the penta-ammine(trimethyl phosphate)iridium(III) ion

P. Hendry and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1984, 164 DOI: 10.1039/C39840000164

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