Issue 1, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

A thermally induced novel fragmentation reaction of transition metal silylcarbene complexes

Ulrich Schubert,   Hannelore Hörnig,   Kai-Uwe Erdmann  and  Karin Weiss  

Abstract

The carbene complexes (CO)5WC(OEt)SiPh3(1) and (CO)5WC(NEt2)SiPh3(2) thermally decompose to give triphenylsilane, ethylene, and W(CO6) or (CO)5WCNEt, respectively, while in the presence of moist CO, [Ph3Si(EtO)CHC(O)]2O is formed, believed to arise via the ketene intermediate, Ph3Si(EtO)C[double bond, length half m-dash]C[double bond, length half m-dash]O.

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Article information

DOI
https://doi.org/10.1039/C39840000013
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 13-14

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A thermally induced novel fragmentation reaction of transition metal silylcarbene complexes

U. Schubert, H. Hörnig, K. Erdmann and K. Weiss, J. Chem. Soc., Chem. Commun., 1984, 13 DOI: 10.1039/C39840000013

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