The X-ray crystal structure of 1-benzoyloxyindole (6), refined to R 0.043, shows that the bonding at nitrogen is distinctly pyramidal, the bond angle sum at nitrogen being 355°.
R. M. Acheson, M. H. Benn, J. Jacyno and J. D. Wallis, J. Chem. Soc., Perkin Trans. 2, 1983, 497 DOI: 10.1039/P29830000497
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