Arylaminomercuriation of terminal acetylenes has been carried out with aliphatic amines to yield amines and enamines. Phenylethynylmercury chloride is shown to be an intermediate in the mercury(II) salt-promoted addition of aliphatic and aromatic amines to terminal alkynes.
J. Barluenga, F. Aznar, R. Liz and R. Rodes, J. Chem. Soc., Perkin Trans. 1, 1983, 1087 DOI: 10.1039/P19830001087
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