Issue 0, 1983
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Formation of a benzobicyclo[4.1.0]heptane lactone by photochemical rearrangement of a steroid ketol. Crystal structure determination of 5-methoxy-des-A-14a-D-homo-14,17-cyclo-oestra-5,7,9-trien-15-one

Alan B. Turner,   R. Alan Howie  and  Philip J. Cox  

Abstract

Photochemical rearrangement of 14β-hydroxy-5-methoxy-des-A-oestra-5,7,9,16-tetraen-15-one (1) gives the cyclopropane-lactone (4), the structure of which was established by X-ray crystallographic analysis. The lactone was isolated by reversed-phase high-performance liquid chromatography. A possible concerted mechanism for its formation is discussed.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P19830000985
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1983, 985-988

Permissions

Request permissions

Formation of a benzobicyclo[4.1.0]heptane lactone by photochemical rearrangement of a steroid ketol. Crystal structure determination of 5-methoxy-des-A-14a-D-homo-14,17-cyclo-oestra-5,7,9-trien-15-one

A. B. Turner, R. A. Howie and P. J. Cox, J. Chem. Soc., Perkin Trans. 1, 1983, 985 DOI: 10.1039/P19830000985

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements