24-Methylene[23,23,25-3H3]cholesterol was transformed by Tenebrio molitor larvae into [23,23,24-3H3]cholesterol; the tritium label distribution in the cholesterol isolated from the larvae compared with that in the administered precursor is in agreement with the migration of hydrogen from C-25 to C-24 during the dealkylation process.
F. Nicotra, F. Ronchetti, G. Russo and L. Toma, J. Chem. Soc., Perkin Trans. 1, 1983, 787 DOI: 10.1039/P19830000787
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