Studies of the infrared spectrum of ytterbium dichloride isolated in an argon matrix demonstrate that the molecule is non-linear. On the basis of chlorine isotope shifts and the relative intensities of ν1 and ν3 the bond angle is estimated to be 126 ± 5°.
I. R. Beattie, J. S. Ogden and R. S. Wyatt, J. Chem. Soc., Dalton Trans., 1983, 2343 DOI: 10.1039/DT9830002343
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