Issue 23, 1983

Novel route to tetrathiafulvalene derivatives via carbon disulphide–iron complexes

Abstract

The (1,3-dithiol-2-ylidene)iron compounds (2), arising from (η2-CS2) Fe complexes, give rise to terrathiafulvalene derivatives either by addition of iodine or by thermolysis; the dimerisation of the carbene ligand requires a vacant co-ordination site on Fe and is inhibited by an increase in CO pressure which allows the formation of the new carbene–iron derivative (5).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1462-1463

Novel route to tetrathiafulvalene derivatives via carbon disulphide–iron complexes

H. Le Bozec and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1983, 1462 DOI: 10.1039/C39830001462

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