3,6,9,12-Tetraoxacyclohexadecane-1,14-dithiol and 3,6,9,12,15-pentaoxaheptadecane-1,17-dithiol are pro-ionophores which can be converted by Fe3+ oxidation into the title compounds which are analogues of 15-crown-5 and 18-crown-6 and which exhibit enhanced ionophoric properties.
M. Raban, J. Greenblatt and F. Kandil, J. Chem. Soc., Chem. Commun., 1983, 1409 DOI: 10.1039/C39830001409
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