Issue 23, 1983

Chemistry of pyrrocorphins: synthesis of isobacteriochlorins and pyrrocorphins bearing a methyl group at the meso position between rings A and D

Abstract

A sigmatropic methyl shift from the angular position C-1 in ring A to the meso position C-20 between rings A and D constitutes the crucial step in syntheses leading to a 20-methyl-isobacteriochlorin and to 20-methyl-pyrrocorphins which served as substrates in the investigation presented in the accompanying communication.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1401-1404

Chemistry of pyrrocorphins: synthesis of isobacteriochlorins and pyrrocorphins bearing a methyl group at the meso position between rings A and D

K. Hilpert, C. Leumann, A. P. Davis and A. Eschenmoser, J. Chem. Soc., Chem. Commun., 1983, 1401 DOI: 10.1039/C39830001401

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