5-Acyl-1,6-diazabicyclo[3.1.0]hexane (1) on treatment with t-butyl hypochlorite affords the corresponding N-chloro-derivative (2) which rearranges easily into 6-acyl-5-chloro-1,6-diazabicyclo[3.1.0]hexane (3) with a 1,2-shift of the acyl group.
S. N. Denisenko, G. V. Shustov and R. G. Kostyanovsky, J. Chem. Soc., Chem. Commun., 1983, 1275 DOI: 10.1039/C39830001275
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