Oxygen–oxygen cleavage in bicyclic trialkylperoxomium ions can account for the mixtures of bicyclic ethers and 2-methoxypropane derivatives obtained from the reaction of 5-t-butylperoxycyclo-octene with N-bromosuccinimide in methanol or with bromine in carbon tetrachloride.
A. J. Bloodworth, J. L. Courtneidge and H. J. Eggelte, J. Chem. Soc., Chem. Commun., 1983, 1267 DOI: 10.1039/C39830001267
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