Issue 20, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Manganese(IV) alkyl complexes. Synthesis and structure of tetramethyl-[1,2-bis (dimethylphosphino)ethane]manganese(IV)

Christopher G. Howard,   Gregory S. Girolami,   Geoffrey Wilkinson,   Mark Thornton-Pett  and  Michael B. Hursthouse  

Abstract

The interaction of tris(acetylacetonato)manganese(III), Mn(acac)3, with methyl-lithium in the presence of 1,2-bis(dimethylphosphino)ethane (dmpe) in diethyl ether leads, in a disproportionation reaction to Mn Me2(dmpe)2 and to Mn Me 4(dmpe) whose X-ray structure has been determined; also synthesised from Mn (acac)3 are MnMe4(PMe3)2 and the green tetrahedral alkyl complexes MnR4, R = CH2SiMe3 and CH2CMe3 which have been identified spectroscopically.

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Article information

DOI
https://doi.org/10.1039/C39830001163
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1163-1164

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Manganese(IV) alkyl complexes. Synthesis and structure of tetramethyl-[1,2-bis (dimethylphosphino)ethane]manganese(IV)

C. G. Howard, G. S. Girolami, G. Wilkinson, M. Thornton-Pett and M. B. Hursthouse, J. Chem. Soc., Chem. Commun., 1983, 1163 DOI: 10.1039/C39830001163

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