Empirical force field calculations for several bicyclic compounds related to sesquinorbornene reveal that the ground state structures are bent at the double bond and that the diastereoisomerization or topomerization barriers may be as high as 6.2 kcal mol–1(25.9 kJ mol–1).
C. A. Johnson, J. Chem. Soc., Chem. Commun., 1983, 1135 DOI: 10.1039/C39830001135
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