The lithium salts of aldehyde t-butylhydrazones react with electrophiles (aldehydes, ketones, alkyl halides) to form C-trapped t-butylazo compounds; isomerisation and hydrolysis gave α-hydroxy ketones and ketones in good yields, thereby providing a convenient new acyl-anion equivalent.
R. M. Adlington, J. E. Baldwin, J. C. Bottaro and M. W. D. Perry, J. Chem. Soc., Chem. Commun., 1983, 1040 DOI: 10.1039/C39830001040
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