New µ-alkylidene complexes [CO2(CO)4(µ-CHR)(µ-dppm)] and [Co2(CO)4(µ-CH2)(µ-CHR)(µ-dppm)], R ![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
H or CO2Et, dppm = Ph2PCH2PPh2, have been prepared by displacement of µ-CO groups from [CO2(CO)4(µ-CO)2(µ-dppm)]on reaction with CHRN2; dynamic n.m.r. data indicate rapid µ-CH2 to terminal methylene transformations in these complexes.
W. J. Laws and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1983, 1020 DOI: 10.1039/C39830001020
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...