Issue 17, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Oxidatively assisted nucleophilic substitution of organosilicon iodides

Abdulaziz I. Al-Wassil,   Colin Eaborn  and  Anil K. Saxena  

Abstract

The iodides (Me3Si)3CSiMe2I, (Me3Si)3CSiPh2I, and But3SiL react with m-chloroperoxybenzoic acid to give the hydroxides (Me3Si)3CSiMe2OH, (Me3Si)2C(SiPh2Me)(SiMe2OH), and But3SiOH, respectively in MeOH (Me3Si)3CSiPh2I suggests the participation of silico-cationic intermediates.

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Article information

DOI
https://doi.org/10.1039/C39830000974
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 974-975

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Oxidatively assisted nucleophilic substitution of organosilicon iodides

A. I. Al-Wassil, C. Eaborn and A. K. Saxena, J. Chem. Soc., Chem. Commun., 1983, 974 DOI: 10.1039/C39830000974

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