Issue 14, 1983

Skeletal characterisation of high nuclearity osmium carbonyl clusters by extended X-ray absorption fine structure (EXAFS) spectroscopy

Abstract

Non-bonded osmium–osmium distances have been identified from the EXAFS of the Os L(III) edge spectra of Os6(CO)18, [N(PPh3)2]2[Os6(CO)18], and [N(PPh3)2]2[Os10C(CO)24] and can be used to characterise the cluster skeleton.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 777-779

Skeletal characterisation of high nuclearity osmium carbonyl clusters by extended X-ray absorption fine structure (EXAFS) spectroscopy

S. L. Cook, J. Evans, G. N. Greaves, B. F. G. Johnson, J. Lewis, P. R. Raithby, P. B. Wells and P. Worthington, J. Chem. Soc., Chem. Commun., 1983, 777 DOI: 10.1039/C39830000777

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