1-(1-Methylcyclopropyl)-3-thioxobutan-1-one, a simple non-aromatic β-thioxoketone, has been found by X-ray diffractometry to exist exclusively in the hydrogen-chelating (Z)-enol form in the crystalline state.
L. Nørskov-Lauritsen, L. Carlsen and F. Duus, J. Chem. Soc., Chem. Commun., 1983, 496 DOI: 10.1039/C39830000496
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