High-yield syntheses of two new types of platinum (II) alkenyl compounds are described: (i) organoboration of trans-[Pt(C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
C–H)2(PEt3)2] with R13B (R1= Me, Et, or Pri) leads to (E,E)-trans-[Pt(CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CR1BR12)2-(PEt3)2] and (ii) organoboration of trans-[Pt(CC–Me)2(PEt3)2] with R13B (R1= Me or Et) leads to (E)-trans-[Pt(CC–Me)(CMe![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CR1BR12)(PEt3)2].
A. Sebald and B. Wrackmeyer, J. Chem. Soc., Chem. Commun., 1983, 309 DOI: 10.1039/C39830000309
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