Issue 2, 1983

Electrochemical behaviour of mixed tetrametallic clusters with Pd2M2 and Pt2M2 cores (M = Cr, Mo, W)

Abstract

Tetrametallic clusters[M1M2(µ3-CO)(µ2-CO)2(C5H5)(PPh3)]2(M1= Pd, Pt; M2= Cr, Mo, W) exhibit an unexpected irreversible two-electron reduction leading to the rupture of the metallic core into identified fragments; in contrast, the first two oxidation waves of the clusters indicate that oxidation occurs in one-electron steps.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 86-88

Electrochemical behaviour of mixed tetrametallic clusters with Pd2M2 and Pt2M2 cores (M = Cr, Mo, W)

R. Jund, P. Lemoine, M. Gross, R. Bender and P. Braunstein, J. Chem. Soc., Chem. Commun., 1983, 86 DOI: 10.1039/C39830000086

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