Enantioselective Grignard addition reactions are described in which magnesium alkoxides derived from 1,2:5,6-di-O-isopropylidene-α-D-allofuranose and 1,6-dideoxy-3,4-O-isopropylidene-2,5-di-C-methyl-L-threo-hexitol are used to provide chiral complexation of the Grignard reagent. A stereochemical interpretation of these and other results is presented.
N. Baggett and R. J. Simmonds, J. Chem. Soc., Perkin Trans. 1, 1982, 197 DOI: 10.1039/P19820000197
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