Acrylonitrile has been examined visually and by i.r. spectroscopy to 50 kbar. The liquid freezes at ca. 11 kbar. There is a phase transformation in the solid near 27 kbar. Above 10 kbar polyacrylonitrile co-exists with the liquid or solid phases: this polymer has an i.r. spectrum closely similar to that from the product of u.v.-induced polymerisation under ambient conditions.
D. M. Adams, L. M. Davey, T. Tan and I. O. C. Ekejiuba, J. Chem. Soc., Faraday Trans. 2, 1982, 78, 1617 DOI: 10.1039/F29827801617
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