Issue 9, 1982
From the journal:

Journal of the Chemical Society, Dalton Transactions

Vibrational spectroscopic studies of trivalent hexa-aqua-cations: single-crystal Raman spectra of caesium aluminium alums between 300 and 1 200 cm–1

Stephen P. Best,   Robert S. Armstrong  and  James K. Beattie  

Abstract

Oriented single-crystal Raman spectra of CsAl(SO4)2·12H2O, CsAl(SeO4)2·12H2O, and CsAl(SO4)2·12D2O have been recorded at 80 K. A complete assignment of the spectra has been made between 300 and 1 200 cm–1 using factor group analysis. All external modes of co-ordinated water for both [Cs(OH2)6]+ and [Al(OH2)6]3+ have been identified. The wavenumbers of the internal modes of [Al(OH2)6]3+ are ν1= 542 cm–1 and ν2= 473 cm–1, with ν5 centred at 347 cm–1.

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Article information

DOI
https://doi.org/10.1039/DT9820001655
Article type
Paper

J. Chem. Soc., Dalton Trans., 1982, 1655-1664

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Vibrational spectroscopic studies of trivalent hexa-aqua-cations: single-crystal Raman spectra of caesium aluminium alums between 300 and 1 200 cm–1

S. P. Best, R. S. Armstrong and J. K. Beattie, J. Chem. Soc., Dalton Trans., 1982, 1655 DOI: 10.1039/DT9820001655

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