X-Ray structural studies reveal that one chloroform guest molecule is embedded in molecular cavity formed by the synthetic large-ring host molecule (1) and is orientated in an unique Key–lock-type arrangement in such a way that the hydrogen atom of the chloroform projects into the centre of the macro-ring.
F. Vögtle, H. Puff, E. Friedrichs and W. M. Müller, J. Chem. Soc., Chem. Commun., 1982, 1398 DOI: 10.1039/C39820001398
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