Issue 21, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray structural characterisation of Mo(S2CNEt2)3(η2-SO2) and evidence for a thionyl chloride complex of MoIII

John A. Broomhead,   Naiad S. Gill,   Brendon C. Hammer  and  Meta Sterns  

Abstract

The reaction of MoCl(S2CNEt2)3 with sulphur dioxide in dichloromethane solution under anaerobic reducing conditions gives both black crystals of the title complex, for which an X-ray structural analysis reveals an S, O bonded η2-SO2 complex, and a second product for which analysis, mass spectral, i.r., and chemical evidence supports formulation as Mo(S2CNEt2)3(SOCl2), the first example of a thionyl chloride complex.

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Article information

DOI
https://doi.org/10.1039/C39820001234
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1234-1235

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Synthesis and X-ray structural characterisation of Mo(S2CNEt2)3(η2-SO2) and evidence for a thionyl chloride complex of MoIII

J. A. Broomhead, N. S. Gill, B. C. Hammer and M. Sterns, J. Chem. Soc., Chem. Commun., 1982, 1234 DOI: 10.1039/C39820001234

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