A high-trans, isotactic polymer of 5,5-dimethylbicyclo[2.2.1]hept-2-ene can be prepared by ring-opening polymerization using (mesitylene)W(CO)3–EtAlCl2, activated by exo-2,3-epoxybicyclo[2.2.1] heptane, and working at low monomer concentration (0.4 mol dm–3) in chlorobenzene solvent at room temperature.
G. I. Devine, H. T. Ho, K. J. Ivin, M. A. Mohamed and J. J. Rooney, J. Chem. Soc., Chem. Commun., 1982, 1229 DOI: 10.1039/C39820001229
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