Brich reductions of the syn-alcohols (1c) and (6)(where the OH group is the substituent on the methano-bridge nearest to the aromatic ring) were atypical in that they were extremely rapid and have products (3) and (7) respectively; these results are explained by the ability of the proximate hydroxy-group to act as an efficient proton source.
E. Cotsaris and M. N. Paddon-Row, J. Chem. Soc., Chem. Commun., 1982, 1206 DOI: 10.1039/C39820001206
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