Issue 19, 1982

Use of the allylic sulphoxide–sulphenate ester rearrangement for the synthesis of a 2-thiacephem and a penem

Abstract

A 2-thioxopenam is synthesised from an acetylthio substituted penem and 2-thiacephem; the letter compound was prepared through the intramolecular nucleophilic capture of an allylic sulphenate ester, generated thermally from the corresponding sulphoxide (1).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1119-1120

Use of the allylic sulphoxide–sulphenate ester rearrangement for the synthesis of a 2-thiacephem and a penem

N. J. Daniels, G. Johnson, B. C. Ross and M. A. Yeomans, J. Chem. Soc., Chem. Commun., 1982, 1119 DOI: 10.1039/C39820001119

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