The hitherto unreported H–D exchange, configurational isomerization, and hydrogenolysis of Z- and E-1,2-dimethylsilacycloalkanes on copper have been studied, and evidence has been obtained for the first time that copper is able to catalyse configurational isomerization.
M. Bartók and Á. Molnár, J. Chem. Soc., Chem. Commun., 1982, 1089 DOI: 10.1039/C39820001089
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