Issue 12, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

A complete model for the catalytic reduction of an alkyne to an alkene by a trinuclear osmium cluster: the X-ray crystal structure of cis-[Os3(CO)11{CF3(H)C:C(H)CF3}]

Zain Dawoodi,   Kim Henrick  and  Martin J. Mays  

Abstract

[HOs3(CO)10{CF3C:C(H)CF3}] reacts with carbon monoxide to give the complexes cis- and trans-[Os3(CO)11–{CF3(H)C:C(H)CF3}], which react further with CO to liberate free alkenes and generate [Os3(CO)12]; an X-ray diffraction study of the cis-isomer is the first for a mono-substituted alkene derivative of a binary metal carbonyl cluster.

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Article information

DOI
https://doi.org/10.1039/C39820000696
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 696-698

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A complete model for the catalytic reduction of an alkyne to an alkene by a trinuclear osmium cluster: the X-ray crystal structure of cis-[Os3(CO)11{CF3(H)C:C(H)CF3}]

Z. Dawoodi, K. Henrick and M. J. Mays, J. Chem. Soc., Chem. Commun., 1982, 696 DOI: 10.1039/C39820000696

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