Issue 12, 1982

Comparison of nucleofugalities in 1, 2- and 1, 3-elimination reactions

Abstract

Ranks ([triple bond, length half m-dash] nucleofugalities) of Br, Cl, OSO2C6H4Me, SO2Ph, SPh, and Oph as leaving groups in sulphonyl-activated cyclopropane-forming eliminations have been determined; a rectilinear correlation between rank and the pka of the conjugate acid of the leaving group is found in direct contrast with behaviour in alkene-forming elimination.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 684-685

Comparison of nucleofugalities in 1, 2- and 1, 3-elimination reactions

B. Issari and C. J. M. Stirling, J. Chem. Soc., Chem. Commun., 1982, 684 DOI: 10.1039/C39820000684

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements