Up to three methylene groups from diazomethane may be incorporated into hydridodiplatinum(I) complexes by insertion into Pt–Pt. Pt–H and, in one case, a Pt–P bond; X-ray structure determination establishes the an M2(µ-CH2) group with no M–M bond are reported.
K. A. Azam, A. A. Frew, B. R. Lioyd, L. Manojlović-Muir, K. W. Muir and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1982, 614 DOI: 10.1039/C39820000614
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