The experimentally observed enantiotopomerization of diarylboron salicylideneaminato-chelates (1) are indicated by model MNDO calculations not to proceed via planar tetraco-ordinate boron transition states (2), but rather by ring opening–ring closure mechanisms.
P. von Ragué Schleyer and E. Würthwein, J. Chem. Soc., Chem. Commun., 1982, 542 DOI: 10.1039/C39820000542
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