New β-substituted homo- and hetero-metallic trianions of the type ![[C with combining macron]](https://www.rsc.org/images/entities/char_0043_0304.gif)
C (![[N with combining macron]](https://www.rsc.org/images/entities/char_004e_0304.gif)
Ph) with alkali metal cations (Li, Na, and K) are obtained from β-substituted organomercury compounds via low temperature mercury–alkali metal transmetallation; the lithiated trianion reacts regioselectively at both carbanionic carbon atoms with electrophilic agents such as D2O, EtBr, Me2S2, and Me3SiCl.
J. A. Barluenga, J. Villamaña, F. J. Fañanás and M. Yus, J. Chem. Soc., Chem. Commun., 1982, 355 DOI: 10.1039/C39820000355
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