Issue 5, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Alkylation and acylation of co-ordinated tertiary phosphines: the nucleophilic substitution of the carbanions derived from [M(CO)4(Ph2PCH2PPh2)](M = Cr, Mo, or W)

Subhi Al-Jibori  and  Bernard L. Shaw  

Abstract

Complexes of the type [M(CO)4(Ph2PCH2PPh2)] are readily deprotonated by strong bases and the resultant carbanions attacked by nucleophiles such as MeI, EtI, CH2: CHCH2Cl, PhCH2Cl, Me3SiCl, Ph2PCl, PhCOCl, or MeC6H4COCl, to effect C-substitution.

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Article information

DOI
https://doi.org/10.1039/C39820000286
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 286-287

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Alkylation and acylation of co-ordinated tertiary phosphines: the nucleophilic substitution of the carbanions derived from [M(CO)4(Ph2PCH2PPh2)](M = Cr, Mo, or W)

S. Al-Jibori and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1982, 286 DOI: 10.1039/C39820000286

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