The new macrocyclic complex of titanium(IV), Ti(C22H22N4)Cl2 has been shown by X-ray crystallography to have a trigonal prismatic co-ordination geometry; the synthesis and reactivities of the peroxo, disulphido, and pyrocatecholato derivatives are discussed.
V. L. Goedken and J. A. Ladd, J. Chem. Soc., Chem. Commun., 1982, 142 DOI: 10.1039/C39820000142
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