The stereochemistry of the C-1 and C-3 adducts formed in the reaction of 1-metallo-1-selenopropionates with cyclohexenone is reported as well as the first evidence in favour of the occurrence of a dissociation into two independent species during the base-promoted isomerization of the C-1 to the C-3 adduct.
J. Lucchetti and A. Krief, J. Chem. Soc., Chem. Commun., 1982, 127 DOI: 10.1039/C39820000127
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