The Hg2+- and TI3+-promoted hydrolyses of the monothioacetal α-ethoxy-α-ethylthiotoluene (1) proceed via the relatively very rapid formation of the hemiacetal (2) whose subsequent hydrolysis controls the observed rate of aldehyde formation.
D. Penn and D. P. N. Satchell, J. Chem. Soc., Chem. Commun., 1982, 54 DOI: 10.1039/C39820000054
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