Issue 10, 1981

Mononuclear heterocyclic rearrangements. Part 7. Evidence for general base catalysis in the rearrangement of the Z-phenylhydrazone of 3-benzoyl-5-phenyl-1,2,4-oxadiazole into 2,5-diphenyl-4-benzoylamino-1,2,3-triazole in dioxan–water

Abstract

The title reaction has been studied at various pS+ and buffer concentrations. Kinetic constants for uncatalysed and catalysed pathways have been calculated. A mechanism for the rearrangement is offered.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1981, 1325-1328

Mononuclear heterocyclic rearrangements. Part 7. Evidence for general base catalysis in the rearrangement of the Z-phenylhydrazone of 3-benzoyl-5-phenyl-1,2,4-oxadiazole into 2,5-diphenyl-4-benzoylamino-1,2,3-triazole in dioxan–water

V. Frenna, N. Vivona, G. Consiglio, A. Corrao and D. Spinelli, J. Chem. Soc., Perkin Trans. 2, 1981, 1325 DOI: 10.1039/P29810001325

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