Equations for the excess adsorption isotherms and the heats of immersion are developed, taking the surface heterogeneity effects of the solids into account. It is shown that taking the heterogeneity effects into account leads to an improvement due to agreement between theory and experiment and provides a new picture of the non-ideality of the adsorbed phase.
W. Rudziński and S. Partyka, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 2577 DOI: 10.1039/F19817702577
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