Issue 5, 1981

Reactions of monomeric difluorosilylene with ethylene

Abstract

Monomeric 31SiF2 reacts efficiently with two molecules of ethylene to give 1,1-difluoro [31Si]silacyclopentane as the final product, but competition experiments indicate that ethylene is about ten times less reactive than buta-1,3-diene for the trapping of the silylene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 217b-218

Reactions of monomeric difluorosilylene with ethylene

E. E. Siefert, S. D. Witt and Y. Tang, J. Chem. Soc., Chem. Commun., 1981, 217b DOI: 10.1039/C3981000217B

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