Issue 21, 1981

Polyhydrido-platinum clusters: synthesis and X-ray crystal structures of [Pt3H6(PBu3t)3], [Pt4H2(PBu3t)4], and [Pt4H8(PPri2Ph)4]

Abstract

Hydrogen reacts with [Pt(C2H4)2(PBu3t)] to give the triangular complex [Pt3H6(PBu3t)3](1) which is dehydrogenated with C2H4 to form the tetrahedral complex [Pt4H2(PBu3t)4](2), whereas [Pt(C2H4)2(PPr2iPh)] reacts with hydrogen yielding directly the four-metal-atom sphenoidal cluster [Pt4H8(PPr2iPh)4](3).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1104-1106

Polyhydrido-platinum clusters: synthesis and X-ray crystal structures of [Pt3H6(PBu3t)3], [Pt4H2(PBu3t)4], and [Pt4H8(PPri2Ph)4]

P. W. Frost, J. A. K. Howard, J. L. Spencer, D. G. Turner and D. Gregson, J. Chem. Soc., Chem. Commun., 1981, 1104 DOI: 10.1039/C39810001104

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