Aliphatic primary and secondary thiols react in the interlamellar layers of ion-exchanged montmorillonite catalysts to produce dialkyl sulphides via intermolecular elimination of hydrogen sulphide; similar processes result in the production of diphenyl sulphide from benzenethiol and poly(phenylenemethylene) from α-toluenethiol.
J. A. Ballantine, R. P. Galvin, R. M. O'Neil, H. Purnell, M. Rayanakorn and J. M. Thomas, J. Chem. Soc., Chem. Commun., 1981, 695 DOI: 10.1039/C39810000695
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