Issue 12, 1981

Optically active trifluoromethylcarbinols as chiral solvating agents for asymmetric transformations at a ring-nitrogen atom

Abstract

Asymmetric chlorination of the nitrogen atom of aziridines can be carried out using achiral t-butyl hypochlorite in the presence of optically active trifluoromethylcarbinols; the absolute stereochemistry of the reaction may be correlated with the chirality of the alcohol used.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 588-590

Optically active trifluoromethylcarbinols as chiral solvating agents for asymmetric transformations at a ring-nitrogen atom

A. Forni, I. Moretti, A. V. Prosyanik and G. Torre, J. Chem. Soc., Chem. Commun., 1981, 588 DOI: 10.1039/C39810000588

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