Issue 11, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

N.m.r. evidence for a fluxional allyl-hydride species featuring an aliphatic C–H … IrIII interaction

Oliver W. Howarth,   Colin H. McAteer,   Peter Moore  and  George E. Morris  

Abstract

The [Ir(H)(PPh3)2(η3-2,3-Dimethylbutenyl)]+ ion has been identified in CD2Cl2 solution from its 1H,2H and 31P n.m.r. spectra, which reveal a novel C–H … IrIII interaction and a fluxional process involving facile hydrogen transfer between metal and hydrocarbon.

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Article information

DOI
https://doi.org/10.1039/C39810000506
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 506-507

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N.m.r. evidence for a fluxional allyl-hydride species featuring an aliphatic C–H … IrIII interaction

O. W. Howarth, C. H. McAteer, P. Moore and G. E. Morris, J. Chem. Soc., Chem. Commun., 1981, 506 DOI: 10.1039/C39810000506

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