Stable nitrile oxides react with Pt(PPh3)2L (L = PPh3,C2H4) to give 1 : 1 products; X-ray studies show that the nitrile oxide is deoxygenated by triphenyl-phosphine and that a phenyl group migrates to the platinum atom to give the complexes [Pt(Ph)(OPPh2)(RCN)(PPh3)].
W. Beck, M. Keubler, E. Leidl, U. Nagel, M. Schaal, S. Cenini, P. Del Buttero, E. Licandro, S. Maiorana and A. C. Villa, J. Chem. Soc., Chem. Commun., 1981, 446 DOI: 10.1039/C39810000446
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