Solid state phase transitions have been discovered in Mn2(CO)10, (ca, 8 kbar), and Re2(CO)10, (ca, 5 kbar) and the Raman spectra ore consistent with a change in molecular geometry from staggered to eclipsed.
D. M. Adams, P. D. Hatton, A. C. Shaw and T. Tan, J. Chem. Soc., Chem. Commun., 1981, 226 DOI: 10.1039/C39810000226
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