A new synthesis of desethylcatharanthine (7b) by utilising a cycloaddition reaction between the 2-(indol-2-yl)acrylate (10) and the N-alkoxycarbonyl-1,2-di-hydropyridine (4b) is described.
C. Marazano, J. Fourrey and B. C. Das, J. Chem. Soc., Chem. Commun., 1981, 37 DOI: 10.1039/C39810000037
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