Mechanism of the reaction of cumyloxyl radicals in a mixture of hydrocarbons
Abstract
Decay reactions of cumyloxyl radicals have been studied in a mixture of cyclohexane and aromatic hydrocarbon. The hydrogen transfer from solvent to oxyl radical increases considerably when small amounts of the aromatic hydrocarbon are present. The addition of cyclohexyl radical to the aromatic ring plays a decisive role in the mechanism of this reaction.
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